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Improving the Strength and Ductility Balance of Al–Ca–(Fe, La, Ce) Ternary Eutectic Alloys by High-Pressure Torsion Processing and Subsequent Annealing

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Abstract

New ternary eutectic aluminum alloys, namely Al–6Ca–3Ce, Al–6Ca–3La, and Al–6Ca–1Fe (wt%) were studied in as-cast state as well as after the high-pressure torsion (HPT) processing and subsequent annealing. It was found that HPT (3 revolutions) formed a nanocrystalline grain/subgrain microstructure or a mixed nano- and submicrocrystalline grain/subgrain microstructure. Moreover, the numerous eutectic particles were refined down to the nanometer range, which led to the formation of multiple stress concentrators and embrittlement of the material. To improve ductility of the alloys, annealing treatment was used. It was shown that annealing at 350 °C (1 h) after HPT resulted in the multiple grain/subgrain growth and predominantly equiaxed grain microstructure formation in all alloys, as well as in the coarsening of some eutectic particles. This caused a decrease in stress concentration. As a result, the strength of the alloy increased and its ductility was restored. The ultimate tensile strength of the Al–6Ca–3Ce, Al–6Ca–3La, and Al–6Ca–1Fe alloys was 455, 422, and 377 MPa, respectively, which was 3.5, 2.2, and 2 times greater than in the as-cast alloys. The relative elongation of the Al–6Ca–3Ce, Al–6Ca–3La, and Al–6Ca–1Fe alloys was 2, 18, and 9%, respectively. Lanthanum, being part of the complex eutectic Al4(Ca, La), ensured high ductility of the alloy, both in the cast state and in the deformed and heat-treated state.

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References

  1. E.A. Naumova, Use of calcium in alloys: from modifying to alloying. Russ. J. Non-Ferrous Metals 59, 284–298 (2018)

    Article  Google Scholar 

  2. N.A. Belov, K.A. Batyshev, V.V. Doroshenko, Microstructure and phase composition of the eutectic Al – Ca alloy, additionally alloyed with small additives of zirconium, scandium and manganese. Non-Ferr. Met. 2017(2), 49–54 (2017)

    Article  Google Scholar 

  3. K. Swaminathan, K.A. Padmanabhan, Tensile flow and fracture behaviour of a superplastic Al–Ca–Zn alloy. J. Mater. Sci. 25, 4579–4586 (1990)

    Article  CAS  Google Scholar 

  4. A.G. Padalko, M.S. Pyrov, O.S. Antonova, Thermal Analysis, Barothermal Treatment, Microstructure, and Properties of an Al–2.5 at % Ca Binary Alloy. Russ. Metall. 2022, 1369–1377 (2022)

  5. J. Yu, Y. Ishiwata, Y. Taguchi, D. Shimosaka, R. Taniguchi, T. Kondo, N. Tezuka, Study of an Al-Ca alloy with low young’s modulus, in Light Metals 2017, ed. by A.P. Ratvik. The Minerals, Metals & Materials Series (Springer, Cham, 2017), pp. 167–171

    Google Scholar 

  6. V. Raghavan, Al-Ca-Mg (aluminum-calcium-magnesium). J. Phase Equilib. Diffus. 32, 52–53 (2011)

    Article  CAS  Google Scholar 

  7. K. Ozturk, L.-Q. Chen, Z.-K. Liu, Thermodynamic assessment of the Al–Ca binary system using random solution and associate models. J. Alloys Compd. 340, 199–206 (2002)

    Article  CAS  Google Scholar 

  8. F. Czerwinski, B. Shalchi Amirkhiz, On the Al–Al11Ce3 eutectic transformation in aluminum–cerium binary alloys. Materials 13, 4549 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. M.P. Moodispaw, E. Cinkilic, J. Miao, A.A. Luo, The beneficial effect of iron in aluminum-cerium-based cast alloys. Metall. Mater. Trans. A 55, 1351–1362 (2024)

    Article  CAS  Google Scholar 

  10. Z. Que, C.L. Mendis, Effects of native AlN particles on heterogeneous nucleation in an Al-3Fe Alloy. Metall. Mater. Trans. A 52, 553–559 (2021)

    Article  CAS  Google Scholar 

  11. L. Wang, R. Qi, B. Ye, Y. Bai, R. Huang, H. Jiang, W. Ding, Improved Tensile Strength of Al-5Ce Alloy by Permanent Magnet Stirring. Metall. Mater. Trans. A 51, 1972–1977 (2020)

    Article  CAS  Google Scholar 

  12. D. Weiss, Improved high-temperature aluminum alloys containing Cerium. J. Mater. Eng. Perform. 28, 1903–1908 (2019)

    Article  CAS  Google Scholar 

  13. N.A. Belov, E.A. Naumova, V.D. Ilyukhin, V.V. Doroshenko, Structure and mechanical properties of Al – 6% ca – 1% Fe alloy foundry goods, obtained by die casting. Tsvetn. Met. 3, 69–75 (2017)

    Article  Google Scholar 

  14. P.K. Shurkin, N.V. Letyagin, A.I. Yakushkova, M.E. Samoshina, D.Y. Ozherelkov, T.K. Akopyan, Remarkable thermal stability of the Al-Ca-Ni-Mn alloy manufactured by laser-powder bed fusion. Mater. Lett. 285, 129074 (2021)

    Article  CAS  Google Scholar 

  15. T.K. Akopyan, N.A. Belov, A.A. Lukyanchuk, N.V. Letyagin, Т.А. Sviridova, A.N. Petrova, A.S. Fortuna, A.F. Musin, Effect of high pressure torsion on the precipitation hardening in Al–Ca–La based eutectic alloy. Mater. Sci. Eng. A 802, 14063 (2021)

    Article  Google Scholar 

  16. T.K. Akopyan, N.V. Letyagin, T.A. Sviridova, N.O. Korotkova, A.S. Prosviryakov, New casting alloys based on the Al+Al4(Ca,La) eutectic. JOM 72, 3779–3786 (2020)

    Article  CAS  Google Scholar 

  17. E.A. Naumova, M.A. Vasina, O.P. Chernogorova, S.O. Rogachev, M.Y. Zadorozhnyi, A.O. Bobrysheva, Investigation of the effect of cerium on the structure and properties of calcium-containing aluminum alloys. Metallurgist 67, 1302–1314 (2024)

    Article  CAS  Google Scholar 

  18. N.V. Letyagin, T.K. Akopyan, P.A. Palkin, S.O. Cherkasov, A.B. Lyukhter, I.S. Pechnikov, Laser welding of aluminum-calcium alloys based on ((Al) + Al4(Ca, La)) eutectic. Metallurgist 68, 692–701 (2024)

    Article  CAS  Google Scholar 

  19. S.O. Rogachev, E.A. Naumova, E.A. Lukina, A.V. Zavodov, V.M. Khatkevich, High strength Al-La, Al-Ce, and Al-Ni eutectic aluminum alloys obtained by high-pressure torsion. Materials 14, 6404 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  20. M.Y. Murashkin, I. Sabirov, A.E. Medvedev, N.A. Enikeev, W. Lefebvre, R.Z. Valiev, X. Sauvage, Mechanical and electrical properties of an ultrafine grained Al-8.5 wt.% RE (RE = 5.4 wt.% ce, 3.1 wt.% La) alloy processed by severe plastic deformation. Mater. Des. 90, 433–442 (2016)

    Article  CAS  Google Scholar 

  21. A.E. Medvedev, M.Y. Murashkin, N.A. Enikeev, I. Bikmukhametov, R.Z. Valiev, P.D. Hodgson, R. Lapovok, Effect of the eutectic Al-(Ce,La) phase morphology on microstructure, mechanical properties, electrical conductivity and heat resistance of Al-4.5(ce,La) alloy after SPD and subsequent annealing. J. Alloys Compd. 796, 321–330 (2019)

    Article  CAS  Google Scholar 

  22. K. Edalati, Z. Horita, A review on high-pressure torsion (HPT) from 1935 to 1988. Mater. Sci. Eng. A 652, 325–352 (2016)

    Article  CAS  Google Scholar 

  23. S.O. Rogachev, A.V. Zavodov, E.A. Naumova, T.V. Chernenok, E.A. Lukina, M.Y. Zadorozhnyy, Improvement of strength–ductility balance of Al–Ca–Mn–Fe alloy by severe plastic deformation. Mater. Lett. 349, 134797 (2023)

    Article  CAS  Google Scholar 

  24. X. Zhang, P. Wu, F. Liang, F. Liu, Achieve high plasticity and strength in 6016 alloy by high-pressure torsion combined with post-aging treatments. J. Mater. Res. Technol. 22, 2967–2982 (2023)

    Article  CAS  Google Scholar 

  25. A.M. Mavlyutov, D.A. Kirilenko, A.A. Levin, M.Y. Murashkin, D.I. Sadykov, T.S. Orlova, Superior strength-ductility synergy in ultrafine-grained Al–5Mg alloy. J. Mater. Res. Technol. 34, 2329–2343 (2025)

    Article  CAS  Google Scholar 

  26. O. Andreau, J. Gubicza, N.X. Zhang, Y. Huang, P. Jenei, T.G. Langdon, Effect of short-term annealing on the microstructures and flow properties of an Al–1% mg alloy processed by high-pressure torsion. Mater. Sci. Eng. A 615, 231–239 (2014)

    Article  CAS  Google Scholar 

  27. R.T. Mathew, S. Singam, P. Ghosh, S.K. Masa, M.J.N.V. Prasad, The defining role of initial microstructure and processing temperature on microstructural evolution, hardness and tensile response of Al-Mg-Sc-Zr (AA5024) alloy processed by high pressure torsion. J. Alloys Compd. 901, 163548 (2022)

    Article  CAS  Google Scholar 

  28. Z. Horita, T. Fujinami, M. Nemoto, T.G. Langdon, Equal-channel angular pressing of commercial aluminum alloys: grain refinement, thermal stability and tensile properties. Metall. Mater. Trans. A 31, 691–701 (2000)

    Article  Google Scholar 

  29. S.O. Rogachev, E.A. Naumova, R.D. Karelin, V.A. Andreev, M.M. Perkas, V.S. Yusupov, V.M. Khatkevich, Structure and mechanical properties of Al–Ca–Mn–Fe–Zr–Sc eutectic aluminum alloy after warm equal channel angular pressing. Russ. J. Non-Ferrous Metals 62, 293–301 (2021)

    Article  Google Scholar 

  30. T.S. Orlova, T.A. Latynina, A.M. Mavlyutov, M.Y. Murashkin, R.Z. Valiev, Effect of annealing on microstructure, strength and electrical conductivity of the pre-aged and HPT-processed Al-0.4Zr alloy. J. Alloys Compd. 784, 41–48 (2019)

    Article  CAS  Google Scholar 

  31. M.M. Castro, L.A. Montoro, A. Isaac, M. Kawasaki, R.B. Figueiredo, Mechanical mixing of mg and zn using high-pressure torsion. J. Alloys Compd. 869, 159302 (2021)

    Article  CAS  Google Scholar 

  32. R. Kulagin, Y. Beygelzimer, Y. Ivanisenko, A. Mazilkin, B. Straumal, H. Hahn, Instabilities of interfaces between dissimilar metals induced by high pressure torsion. Mater. Lett. 222, 172–175 (2018)

    Article  CAS  Google Scholar 

  33. S.O. Rogachev, S.A. Nikulin, V.M. Khatkevich, R.V. Sundeev, A.A. Komissarov, Features of structure formation in layered metallic materials processed by high pressure torsion. Metall. Mater. Trans. A 51, 1781–1788 (2020)

    Article  Google Scholar 

  34. Y. Beygelzimer, Y. Estrin, A. Mazilkin, T. Scherer, B. Baretzky, H. Hahn, R. Kulagin, Quantifying solid-state mechanical mixing by high-pressure torsion. J. Alloys Compd. 878, 160419 (2021)

    Article  CAS  Google Scholar 

  35. Y. Ivanisenko, W. Lojkowski, R.Z. Valiev, H.-J. Fecht, The mechanism of formation of nanostructure and dissolution of cementite in a pearlitic steel during high pressure torsion. Acta Mater. 51, 5555–5570 (2003)

    Article  CAS  Google Scholar 

  36. X. Sauvage, F. Cuvilly, A. Russell, K. Edalati, Understanding the role of Ca segregation on thermal stability, electrical resistivity and mechanical strength of nanostructured aluminum. Mater. Sci. Eng. A 798, 140108 (2020)

    Article  CAS  Google Scholar 

  37. A.M. Glezer, R.V. Sundeev, A.V. Shalimova, L.S. Metlov, Physics of severe plastic deformation. Phys.-Usp. 66, 32–58 (2023)

    Article  CAS  Google Scholar 

  38. Y. He, J. Liu, S. Qiu, Z. Deng, J. Zhang, Y. Shen, Microstructure evolution and mechanical properties of Al-La alloys with varying La contents. Mater. Sci. Eng. A 701, 134–142 (2017)

    Article  CAS  Google Scholar 

  39. S.O. Rogachev, V.A. Andreev, M.A. Barykin, A.V. Doroshenko, R.D. Karelin, V.S. Komarov, E.A. Naumova, N.Y. Tabachkova, Structure and mechanical properties of Al-Ca-(Fe, La) eutectic alloys after equal-channel angular pressing. Lett. Mater. 14, 167–172 (2024)

    Google Scholar 

  40. S.O. Rogachev, E.A. Naumova, Thermal stability of Al-Ca and Al-Ce alloys obtained by high-pressure torsion. J. Mater. Eng. Perform. 30, 9192–9199 (2021)

    Article  CAS  Google Scholar 

  41. A.S. Sigov, N.D. Golovanova, O.A. Minaeva, S.I. Anevsky, R.V. Shamin, O.I. Ostanina, Solution of topical spectroradiometric problems using synchrotron radiation. Russian Technological J. 10(3), 34–44 (2022)

    Article  Google Scholar 

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Acknowledgements

This work was supported by Moscow Polytechnic University within the framework of the P.L. Kapitsa grant program. We thank M.A. Barykin for his help in preparing the castings.

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Authors and Affiliations

  1. National University of Science and Technology MISIS, Moscow, Russia

    Stanislav O. Rogachev, E. A. Naumova & N. Yu. Tabachkova

  2. Baikov Institute of Metallurgy and Materials Science of Russian Academy of Sciences, Moscow, Russia

    Stanislav O. Rogachev

  3. Russian Technological University “MIREA”, Moscow, Russia

    R. V. Sundeev

  4. Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia

    N. Yu. Tabachkova

  5. Moscow Polytechnic University, Moscow, Russia

    M. Yu. Zadorozhny

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  1. Stanislav O. Rogachev
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  2. E. A. Naumova
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Contributions

S.O. Rogachev: Conceptualization, Writing—original draft, Investigation, Formal analysis. E.A. Naumova: Writing—review & editing, Methodology, Validation, Resources. R.V. Sundeev: Writing—review & editing, Methodology. N.Yu. Tabachkova: Investigation, Visualization. M.Yu. Zadorozhny: Investigation, Visualization, Funding acquisition.

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Correspondence to Stanislav O. Rogachev.

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Rogachev, S.O., Naumova, E.A., Sundeev, R.V. et al. Improving the Strength and Ductility Balance of Al–Ca–(Fe, La, Ce) Ternary Eutectic Alloys by High-Pressure Torsion Processing and Subsequent Annealing. Met. Mater. Int. 31, 2992–3006 (2025). https://doi.org/10.1007/s12540-025-01917-8

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